Nalco -1800 -corrosion Inhibitor 2h2ph

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

1.

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME :

Tri-ACT® 1800

APPLICATION :

BOILER STEAM CONDENSATE TREATMENT

COMPANY IDENTIFICATION :

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, The Netherlands

EMERGENCY TELEPHONE NUMBER(S) :

See section 16, for Emergency Telephone Numbers.

Date issued : Version Number :

06.10.2010 5.0

COMPANY TELEPHONE NUMBERS. NALCO EUROPE B.V. NALCO AB (SE)

+31 71 5241 100 +46 (0)31-707 22 70

NALCO NORGE AS (NO) Distributor Nalco Mobotec Polska Sp. z o.o.

NALCO ANADOLU KIMYA (TR) NALCO APPLIED SERVICES OF EUROPE BV NALCO BELGIUM BVBA NALCO DANMARK ApS NALCO DEUTSCHLAND GmbH (D) NALCO ESPAÑOLA S.L. (E)

+90 216 5743464 +31 (0)73 6456980

NALCO PORTUGUESA LDA. (P) NTD S.r.l (IT)

+32 (0)3-450 69 10 +45-48195800 +49 (0)69-79340

Nalco Switzerland AG (CH) Nalco Company OOO NALCO ÖSTERREICH Ges.m.b.H. (A) First Distributor: Nalco Czechia s.r.o. (CZ)

+34 93-4095555

NALCO FINLAND OY (FI)

+358 (0)9 2519 5600

NALCO SAS

+33 (0)3 20 11 70 00

NALCO HELLAS S.A. (GR)

+30 210 238 9620

NALCO ITALIANA S.R.L.(I) NALCO NETHERLANDS B.V.

+39 06-54565000 +31 (0)13-5952200

Local : Nalco Hungary Kft. (HU) Local : Nalco Österreich Ges.m.b.H., Representation Office Predstavnistvo Zagreb (HR) Local : Nalco Österreich Ges.m.b.H. Representation Office ROMANIA (RO) NALCO LIMITED

+47 51 96 36 00 PRZEMYS ŁOWA 55 PL-43-110 TYCHY TEL:+48 (0)32-3262750 FAX: +48(0)32 329 13 11 e-mail: [email protected] +351 214121852 +39 (0) 313351325 +41 (0)52 235 38 38 +7 (0)495 980 72 80 + 43(0)1 27026350 Hlavní 1222/60,141 00 Praha 4,Czech Republic,+420 267 912 350 & +420 272 913 512 +36 1 8805610 +385 (0)1 377 95 21 +40 (0) 21 224 17 93 +44 (0)1606 74488

For Product Safety information please Jacqueline Dudley, e-mail [email protected]

2.

HAZARDS IDENTIFICATION

HAZARD CLASSIFICATION : This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Causes burns. May cause sensitization by skin . Harmful in with skin and if swallowed. Possible risk of impaired fertility. HUMAN HEALTH HAZARDS - ACUTE :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 1 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

INHALATION : Irritating, in high concentrations, to the eyes, nose, throat and lungs. Vapors may have a strong offensive odor which may cause sensory response including headache, nausea and vomiting. SKIN : May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid istered. Harmful if absorbed through skin. May cause sensitization by skin . EYE : Corrosive. Will cause eye burns and permanent tissue damage. Exposure to low vapor concentrations can result in foggy or blurred vision, objects appearing bluish and appearance of a halo around lights. These symptoms are temporary. INGESTION : Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. Harmful if swallowed. HUMAN HEALTH HAZARDS - CHRONIC : Possible risk of impaired fertility.

3.

COMPOSITION/INFORMATION ON INGREDIENTS

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Hazardous Substance(s)

CAS NO

SYMBOL

Cyclohexylamine

EINECS / ELINCS NO 203-629-0

108-91-8

C

Monoethanolamine Methoxypropylamine

205-483-3 226-241-3

141-43-5 5332-73-0

C C

R-PHRASES / NOTAS R10, R21/22, R34, R62 R20/21/22, R34 R10, R22, R35, R43, R52

% (w/w) 5 - < 10 10 - < 20 10 - < 20

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

4.

FIRST AID MEASURES

INHALATION : Remove to fresh air, treat symptomatically. Get medical attention. SKIN : Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Get immediate medical attention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use. EYE : PROMPT ACTION IS ESSENTIAL IN CASE OF . Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get immediate medical attention. INGESTION : DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get immediate medical attention. NOTE TO PHYSICIAN :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 2 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5.

FIRE FIGHTING MEASURES

FLASH POINT :

57 °C PMCC

EXTINGUISHING MEDIA : Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning material. Water mist may be used to cool closed containers. FIRE AND EXPLOSION HAZARD : Flammable Liquid; may release vapors that form flammable mixtures at or above the flash point. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6.

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water.

7.

HANDLING AND STORAGE

HANDLING : Do not get in eyes, on skin, on clothing. Do not take internally. Do not breathe vapors/gases/dust. Use with adequate ventilation. Avoid generating aerosols and mists. Keep away from acids and oxidizing agents. Do not use, store, spill or pour near heat, sparks or open flame. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. STORAGE CONDITIONS : Store the containers tightly closed. Store away from heat and sources of ignition. Use proper grounding procedures. Store separately from acids. Store separately from oxidizers. Amine and sulphite products should not be stored within close proximity or resulting vapors may form visible airborne particles. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 3 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

SUITABLE CONSTRUCTION MATERIAL : HDPE (high density polyethylene), Natural rubber, Polypropylene, Stainless Steel 304, Stainless Steel 316L, Surface-modified HDPE (high density polyethylene), PTFE, Perfluoroelastomer, Fluoroelastomer, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use. UNSUITABLE CONSTRUCTION MATERIAL : Carbon Steel C1018, Epoxyresin coating SPECIFIC USE(S) : BOILER STEAM CONDENSATE TREATMENT For specific dosages and customized applications please your representative.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source AUSTRIA

BELGIUM

BULGARIA

DENMARK

Substance(s) Cyclohexylamine

Category: MAK MAK CEIL Skin*

ppm 10 10

mg/m3 40 40

Monoethanolamine

MAK MAK STEL Skin*

1 3

2.5 7.6

Cyclohexylamine

TWA

10

42

Monoethanolamine

TWA STEL Skin*

1 3

2.5 7.6

Cyclohexylamine

TWA

20

Monoethanolamine

TWA STEL

8 15

Cyclohexylamine

GV Skin* GV Skin*

Monoethanolamine

FINLAND



10

40

10

GV Skin* GV Skin*

1

2.5

Cyclohexylamine

HTP 8H HTP 15MIN Skin*

1 10

4.1 41

Monoethanolamine

HTP 8H HTP 15MIN Skin*

1 3

2.5 7.6

Cyclohexylamine

VME Skin*

10

40

1

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 4 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers. Monoethanolamine

VME VLE Skin*

1 3

2.5 7.6

Cyclohexylamine

MAK

2

8.2

Monoethanolamine

AGW Skin*

2

5.1

Cyclohexylamine

TWA Skin*

10

40

Monoethanolamine

TWA STEL

3 6

8 15

ITALY

Monoethanolamine

TWA STEL Skin*

1 3

2.5 7.6

NETHERLANDS

Monoethanolamine

TGG TGG 15 Skin*

NORWAY

Cyclohexylamine

. NORM Skin*

10

40

Monoethanolamine

. NORM . NORM Skin*

3 1

8 2.5

Cyclohexylamine

VLA-ED

10

41

Monoethanolamine

VLA-ED VLA-EC Skin*

1 3

2.5 7.5

Cyclohexylamine

NGV KTV

5 10

20 40

Monoethanolamine

NGV KTV Skin*

3 6

8 15

Cyclohexylamine

TWA STEL Skin*

2 4

8.2 16.4

Monoethanolamine

TWA STEL

2 4

5 10

Cyclohexylamine

TWA

10

41

Monoethanolamine

TWA STEL Skin*

1 3

2.5 7.6

Cyclohexylamine

MAC-NDS MAC-NDSC h

40 80

Monoethanolamine

MAC-NDS MAC-NDSC h

2.5 7.5

Cyclohexylamine

ÁK CK

40 40



IRELAND

SPAIN

SWEDEN

SWITZERLAND

UNITED KINGDOM

POLAND

HUNGARY

2.5 7.6

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

LATVIA

CZECH REPUBLIC

CROATIA

ROMANIA

RUSSIAN FEDERATION

SERBIA

SLOVAKIA

SLOVENIA

Monoethanolamine

ÁK CK Skin*

2.5 7.6

Cyclohexylamine

TWA

1

Monoethanolamine

TWA

0.5

Cyclohexylamine

PEL NPK-P Skin*

20 40

Monoethanolamine

PEL NPK-P Skin*

2.5 7.5

Cyclohexylamine

GVI

10

41

Monoethanolamine

GVI KGVI Skin*

1 3

2.5 7.6

Cyclohexylamine

TWA STEL

5 10

20 40

Monoethanolamine

TWA STEL Skin*

1 3

2.5 7.6

Cyclohexylamine (Vapour.)

CEIL

1

Monoethanolamine (Vapor and aerosol.)

CEIL

0.5

Cyclohexylamine

MAC Skin*

10

40

Monoethanolamine

MAC Skin*

3

8

Cyclohexylamine

TWA CEILING

2

8.2 16.4

Monoethanolamine

TWA CEILING Skin*

1

2.5 7.6

Cyclohexylamine

TWA STEL MULT Skin*

10

41

Monoethanolamine

STEL MULT Skin* TWA

1

2.5

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes.

MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant Cyclohexylamine US NIOSH: 2010 Gas chromatography Silica gel

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 6 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

Monoethanolamine

US NIOSH: 2007

Methoxypropylamine

No method identified

Gas chromatography

Silica gel

ENGINEERING MEASURES : General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387. Consider the use of filter type: AX-P In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN 14605 and EN ISO 20345. EYE PROTECTION : Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

9.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

Liquid

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

APPEARANCE

Light yellow

ODOR

Amine

FLASH POINT : SPECIFIC GRAVITY SOLUBILITY IN WATER pH (100 %) VISCOSITY MELTING POINT

57 °C PMCC 0.99 (25 °C) ASTM D-1298 Complete 12.8 5 s (25 °C) ASTM D-2983 -13.33 °C ASTM D-1177

Note: These physical properties are typical values for this product and are subject to change.

10.

STABILITY AND REACTIVITY

STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID : Heat and sources of ignition including static discharges. MATERIALS TO AVOID : with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors., Strong acids, with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors., Avoid with SO2 or acidic bisulfite products, which may react to form visible airborne amine salt particles. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon, Oxides of nitrogen

11.

TOXICOLOGICAL INFORMATION

The following results are for the product. The following results are for the hazardous components. ACUTE ORAL TOXICITY : Species: Rat LD50: 1,267 mg/kg Test Descriptor: Product ACUTE DERMAL TOXICITY : Species: Rabbit LD50: 400 - 2,000 mg/kg Test Descriptor: Hazardous component Monoethanolamine Species: LD50: Test Descriptor:

Rabbit > 2,000 mg/kg Product

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

ACUTE INHALATION TOXICITY : Species: Rat LC50: 8000 PPM (4 hrs) Test Descriptor: Hazardous component Cyclohexylamine PRIMARY SKIN IRRITATION : Species: Rabbit Draize Score: /8.0 Test Descriptor: Similar Product Remarks:

Causes burns.

PRIMARY EYE IRRITATION : Remarks: Causes burns. SENSITIZATION : Methoxypropylamine is reported to cause skin sensitization in guinea pigs. CARCINOGENICITY : Possible risk of impaired fertility. For additional information on the hazard of the preparation, please consult section 2 and 12.

12.

ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS : The following results are for the product. ACUTE FISH RESULTS : Species Exposure Rainbow Trout 96 hrs Fathead Minnow 96 hrs Inland Silverside 96 hrs

LC50 200 mg/l 194 mg/l 1,464.3 mg/l

ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 Daphnia magna 48 hrs 326 mg/l Mysid Shrimp (Mysidopsis bahia)

96 hrs

614.0 mg/l

NOEC 150 mg/l 150 mg/l

Method

Test Descriptor Product Product Product

EC50 250 - 400 mg/l

Method

Test Descriptor Product Product

PERSISTENCY AND DEGRADATION : Chemical Oxygen Demand (COD) : 524,000 mg/l

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

Biological Oxygen Demand (BOD) : Incubation Period Value 6,400 mg/g

Method

Test Descriptor Product

The organic portion of this preparation is expected to be readily biodegradable. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

13.

DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. This product is ashless and can be burned directly in appropriate equipment. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is NOT suitable for disposal by either landfill or via municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous substances. If this product is used in any further processes, the final must redefine and assign the most appropriate European Waste Catalogue Code. NATIONAL REGULATIONS AUSTRIA : Waste Code :55352 NATIONAL REGULATIONS CZECH REPUBLIC Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No. 477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. 381/2001 Coll.), as amended NATIONAL REGULATIONS POLAND : Waste Code: Regulations of 27 September 2001, Waste catalogue, J. of Laws No. 112, item 1206. Act of 22 January 2010 amending the Act on waste and certain other acts (J.oL. no. 28, item 145.) Directive 2006/12/EC of the European Parliament and of the Council of 5 April 2006 on waste. 91/689/EEC Council Directive of 12 December 1991 on hazardous waste. 94/62/EC Directive of the European Parliament and of the Council of 20 December 1994 on packaging and packaging waste. Do not dispose into a local sewage system or with normal household waste. Do not dispose into municipal drains, sewers, soil, natural streams or rivers. The waste product should be disposed of at an authorised incineration plant or a waste treatment/disposal plant in line with the existing regulations (Act of 27 April 2001 on Waste, consolidated text annexed to the J. of Laws No. 39, item 251 of 2007). The product incineration produces ash. The product may be incinerated directly using suitable equipment. Reclamation, recycling and disposal of packaging waste should comply with the existing regulations (Act of 11 May 2001 on Packaging and Packaging Waste, J. of Laws No. 63, item 638, as amended). Use the services of appropriately authorised businesses. Decree about waste of 27.04.2001 (DZ.U nr.62 item 628 with later changes Dz U 2003, nr 7 item 78

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

14.

TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Hazard Class - Secondary : Packing Group : ADR/RID H.I.n. : CLASSIFICATION CODE :

AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Methoxypropylamine, Cyclohexylamine UN 2734 8 3 II 83 CF1

AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Hazard Class - Secondary : Packing Group : IATA Cargo Packing Instructions : IATA Cargo Aircraft Limit : IATA enger Packing Instructions : IATA enger Aircraft Limit :

AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Methoxypropylamine, Cyclohexylamine UN 2734 8 3 II 812 30 L (Max net quantity per package) Y808 / 808 0.5 L / 1 L

MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Hazard Class - Secondary : Packing Group :

AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. Methoxypropylamine, Cyclohexylamine UN 2734 8 3 II

OTHER APPLICABLE INFORMATION CEFIC TREMCARD REFERENCE : EMERGENCY ACTION CODE :

80GCF1-II 2W

15.

REGULATORY INFORMATION

CLASSIFICATION AND LABELLING : GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations Directive 1999/45/EC. HAZARD SYMBOLS

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

CORROSIVE Contains:..Methoxypropylamine Cyclohexylamine Monoethanolamine RISK PHRASES R34 - Causes burns. R43 - May cause sensitization by skin . R21/22 - Harmful in with skin and if swallowed. R62 - Possible risk of impaired fertility. SAFETY PHRASES S24/25 - Avoid with skin and eyes. S26 - In case of with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). NATIONAL REGULATIONS CZECH REPUBLIC This preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. 356/2003 Coll.) This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and per Act 371/2008 Coll. Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No. 178/2001 Coll. laying down conditions of health protection of employees at work NATIONAL REGULATIONS Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s): 49, 49 bis Special medical supervision - Decree of 11 July 1977: Relevant. Classified Industrial Sites (IE): Relevant. Headings: 1432B NATIONAL REGULATIONS WGK 1 (Annex 4) NATIONAL REGULATIONS HOLLAND ABM RESULT ABM RESULT Substance(s) 9B

% (w/w)

NATIONAL REGULATIONS HUNGARY Relevant and applicable Hungarian legislation on protection of human health and the environment:

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SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

Decree 44/2000. (XII.27.) EüM (Minister of Health Affairs) and its amendments: Decree 33/2004. (IV.26.) ESzCsM (Minister of Health, Social and Family Affairs) and Decree 26/2007. (VI.7.) EüM (1907/2006/EK - REACH) on detailed rules of certain procedures and activities related to dangerous substances and preparations. t Ministerial Decree: 25/2000. (IX.30.) EüM-ESzCsM on chemical safety at work. NATIONAL REGULATIONS POLAND Act on chemical substances and preparations of 11 January 2001 (J.oL. No. 11, item 84 as amended). Unified text (J.oL of 2009, No 152, item 1222). Minister of Health Regulation of 8 February 2010 concerning a list of dangerous substances including classification and labelling (J.oL. no. 27 item 140). Minister of Health Regulation of 2 September 2003 concerning criteria and way of classification of chemical substances and preparations (J.oL. No 171, item 1666 as amended). Minister of Health Regulation of 5 March 2009 concerning labelling of dangerous substances and preparations (J.oL. no. 53 item 439). Regulation of MPiPS [Minister of Labour and Social Policy] dated 29 November 2002 on maximum allowable concentrations and levels of harmful factors in the working environment (J.oL. No. 217, item 1833 as amended). Government Statement dated 16 January 2009 on introduction of changes in appendices A and B to European Agreement on road transport of hazardous goods (ADR) prepared in Geneva on 30 September 1957 (J.oL. No 27, item 162). Minister of Economy Regulation of 21 December 2005 on essential requirements for Personal Protective Equipment (J.oL. No. 259, item 2173 of 2005).Minister of Health Regulation of 20 April 2005 on tests and measurements of factors hazardous for health in the working environment (J.oL. No. 73, item 645 dated 2005 as amended). Regulation 1907/2006/EC concerning Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and No 1488/94, as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC Regulation 1272/2008/EC of the European Parliament and of the Council of 16 December 2008 on the classification, labelling and packaging of substances and mixtures, amending and repealing Directive 67/548/EEC and 1999/45/EC and amending Regulation (EC) No 1907/2006.1999/45/EC Directive of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and istrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations.790/2009/EC Commission Regulation of 10 August 2009 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures.453/2010/ EC Commission regulation of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning Registration, Evaluation, Authorization and Restriction of Chemicals (REACH). NATIONAL REGULATIONS RUSSIAN FEDERATION The law of Russian Federation "About the sanitary-epidemiological safety of the population", 30 March 1999 N 52-FZ. The law of Russian Federation "About the safety of the dangerous industrial objects", 21 July 1997 No. 116-FZ. The law of Russian Federation "About protection of the rights of the consumers", 07 February 1992 N 2300-1. The law of Russian Federation "Basics of the legislation of The law of Russian Federation "About the industrial regulation", 27 December 2002 N 184-FZ. The law of Russian Federation "On Environmental Protection", 10 January 2002, N 7-FZ. GOST 30333-2007: Chemical production safety port. General requirements. GOST 19433-88: Dangerous goods. Classification and marking. GOST 12.1.007-76 (Occupational safety standards system. Noxious substances. Classification and general safety requirements). PRODUCT REGISTRATION NUMBER NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 13 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

Denmark

1784346

INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. Safety Data Sheet according to Regulation (EC) No 1907/2006. Nalco is committed to and fully s the Registration, Evaluation, Authorization and restriction of CHemicals (REACH) regulation. It is our intention to pre- all chemical substances that we manufacture or import into European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment. Should you require any further information on Nalco's REACH programme please us at [email protected] or visit our website. UNITED STATES : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).

16.

OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3 R10 - Flammable. R20 - Harmful by inhalation. R21/22 - Harmful in with skin and if swallowed. R22 - Harmful if swallowed. R34 - Causes burns. R35 - Causes severe burns. R43 - May cause sensitization by skin . R52 - Harmful to aquatic organisms. R62 - Possible risk of impaired fertility. - REVISED INFORMATION: section(s): -2 -3 -8 - 11 - 15 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 14 / 15

SAFETY DATA SHEET PRODUCT

Tri-ACT® 1800 EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

EMERGENCY TELEPHONE NUMBER(S) Trans-European Belgium / Luxembourg Bulgaria Croatia Czech Republic Denmark Finland / French Switzerland / Austria / German Switzerland Hungary Italy / Italian Switzerland Latvia The Netherlands Norway Poland Portugal Romania Russia / Belarus Saudi Arabia Serbia Slovak Republic Slovenia Spain Sweden UAE UK and Republic of Ireland Nalfleet International

+32-(0)3-575-5555 +32-(0)3-575-0330 +32-(0)3-575-5555 +385 (0)91-1-25-75-23 +420-602-669421 +47-22-33-69-99 +358-(0)9-471 977 +33-(0)6-11-07-32-81 +49-(0)6232-130128 +36-30-9-506-447 +39-333-210-7947 +32-(0)3-575-5555 & Local emergency telephone number 112 +32-(0)3-575-0330 +47-22-33-69-99 +48-(0)601-66-2626 (SGS) / +48(0)14 637 40 81 (SPOT) +351-91-911-1399 +40-744 -34-14-53 +7-812-449-0474 +966-(3)847-1515 +32-(0)3-575-5555 +421-(0)905-585-938 +386-41-634-916 +34-977-551577 +47-22-33-69-99 +44-(0)7071-223-738 +44-(0)7071-223-738 +32-(0)3-575-5555

POISON CONTROL CENTER TELEPHONE NUMBERS Belgium Czech Republic Hungary Latvia Slovak Republic

+32-70-245245 +420 224 91 92 93 +33-(0)145-42-59-59 ORFILA +36-80-201-199 (ETTSZ, 1096 Budapest, Nagyvárad tér 2) + 371 67042473 +421 (0)2 5477 4166

Prepared By : SHE Department Date issued : 06.10.2010 Version Number : 5.0 Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100 For additional copies of an MSDS visit www.nalco.com and request access 15 / 15