Electrochemical Impedance Analysis And Interpretat 5zt2u

See discussions, stats, and author profiles for this publication at: https://idoc-pub.descargarjuegos.org/publication/235934471

Electrochemical Impedance: Analysis and Interpretation Book · January 1993 DOI: 10.1520/STP1188-EB

CITATIONS

READS

111

1,842

3 authors, including: Martin Kendig Kendig Research Associates 138 PUBLICATIONS 2,716 CITATIONS SEE PROFILE

Some of the authors of this publication are also working on these related projects:

Corrosion Protection by Organic Coatings View project

Corrosion Inhibition View project

All content following this page was ed by Martin Kendig on 10 September 2015.

The has requested enhancement of the ed file.

STP 1188

Electrochemical Impedance: Analysis and Interpretation John R. Scully, David C. Silverman, and Martin W. Kendig, Editors

ASTM Publication Code Number (PCN): 04-011880-27

1916 Race Street Philadelphia, PA 19103

Library of Congress Catag-in-Publication Data Electrochemical impedance : analysis and interpretation / John R. Scully, David C. Silverman, and Martin W. Kendig, editors. (STP ; 1188) "ASTM publication code number (PCN) : 04-011880-27." Includes bibliographical references and indexes. ISBN 0-8031-1861-9 1. Corrosion and anti-corrosives. 2. Electric resistance--Data processing. 3. Electrochemical analysis--Data processing. I. Scully, John R., 1958II. Silverman, David C., 1947III. Kendig, Martin W. IV. Series: ASTM special technical publication ; 1188. TA418.74.E43 1993 620. l' 1223--dc20 92-42059 CIP

Copyright 9 1993 AMERICAN SOCIETY FOR TESTING AND MATERIALS, Philadelphia, PA. All rights reserved. This material may not be reproduced or copied, in whole or in part, in any printed, mechanical, electronic, film, or other distribution and storage media, without the written consent of the publisher.

Photocopy Rights Authorization to photocopy items for internal or personal use, or the internal or personal use of specific clients, is granted by the AMERICAN SOCIETY FOR TESTING AND MATERIALS for s ed with the Copyright Clearance Center (CCC) Transactional Reporting Service, provided that the base fee of $2.50 per copy, plus $0.50 per page is paid directly to CCC, 27 Congress St., Salem, MA 01970; (508) 744-3350. For those organizations that have been granted a photocopy license by CCC, a separate system of payment has been arranged. The fee code for s of the Transactional Reporting Service is 0-8031-1861-9-93 $2.50 + .50.

Peer Review Policy Each paper published in this volume was evaluated by three peer reviewers. The authors addressed all of the reviewers' comments to the satisfaction of both the technical editor(s) and the ASTM Committee on Publications. The quality of the papers in this publication reflects not only the obvious efforts of the authors and the technical editor(s), but also the work of these peer reviewers. The ASTM Committee on Publications acknowledges with appreciation their dedication and contribution to time and effort on behalf of ASTM.

Printed in Fredericksburg,VA March 1993

Foreword This publication, Electrochemical Impedance: Analysis and Interpretation, contains papers presented at the symposium of the same name, held in San Diego, CA on 4-5 November 1991. The symposium was sponsored by ASTM Committee G-1 on Corrosion of Metals. John R. Scully, University of Virginia, Center for Electrochemical Science and Engineering, David C. Silverman, Monsanto, and Martin W. Kendig, Rockwell International Science Center, presided as symposium chairmen and are editors of the resulting publication.

Contents Overview

MODELING AND CORROSIONPROCESSES Impedance Spectra Calculated from Model Polarization C u r v e s - - u . BERTOCCI AND R. E. RICKER Discussion

9 22

Specific Aspects of Impedance Measurements in Low Conductivity M e d i a - s. CHECH]RLIAN, M. KEDDAM, AND H. TAKENOUTI

23

Analysis of EIS Data for Common Corrosion Processes--F. MANSFELD, H. SHIH, H. GREENE, AND C. H. TSAI

37

Analyzing Simulated Electrochemical Impedance Spectroscopy Results by the Systematic Permutation of Data Points--P. R. ROBERGE

54

The Effect of Parasitic Conduction Pathways on EIS Measurements in Low Conductivity Media--K. C. STEWART, D. G. KOLMAN, AND S. R. TAYLOR

73

The Characterization of the Coarsening of Dealloyed Layers by EIS and Its Correlation with Stress-Corrosion Cracking--R. G. KELLY, A. J. YOUNG, AND R. C. NEWMAN

94

APPLICATIONS OF KRAMERS-KRONIGTRANSFORMATIONS Application of the Kramers-Kroulg Relations in Electrochemical Impedance SpeetroscopymP. AGARWAL, M. E. ORAZEM, AND L. H. GARCIA-RUBIO

115

Kramers-Kronig Transformation in Relation to the Interface Regulating Devicem C. GABRIELLI, M. KEDDAM, AND H. TAKENOUTI

140

Validation of Experimental Data from High Impedance Systems Using the Kramers-Kronig TransformsmB. J. DOUGHERTY AND S. I. SMEDLEY

154

CORROSION AND INHIBITION The Impedance Response of Film-Covered Metals--s. TURGOOSE AND R. A. COTTIS

173

Corrosion Prediction from Circuit Models Application to Evaluation of Corrosion InhibitorsbD. c. SILVERMAN

192

Use of Electrochemical Noise in the Study of Inhibitor Systems: Part I--The Effect of Silicate Polymerization on the Inhibition of Aluminum--s. T. HIROZAWA 205

AND D. E. TURCOTTE The Influence of Corrosion Product Film Formation on the Corrosion of CopperNickel Alloys in Aqueous NaCI--H. HACK AND H. PICKERING

220 236

Discussion Interpreting Electrochemical Impedance Spectra from Segmented Electrode Arrangements--A. N. ROTHWELL, J. L. DAWSON, D. A. EDEN, AND J. W. PALMER

237 251

Discussion

CORROSION OF ALUMINUM Evolution of Electrochemical Impedance During Sealing of Porous Anodic Films on Aluminum--J. L. DAWSON, G. E. THOMPSON, AND M. B. H. AHMADUN

255 275

Discussion Characterization of the Corrosion of Aluminum Thin Films Using Electrochemical Impedance Methods--J. R. SCULLY

276

Detection and Monitoring of Localized Corrosion by E I S - - F . MANSFELD, Y. WANG, S. H. LIN, H. XIAO, AND H. SHIH

297

Potentiodynamic Polarization and Electrochemical Impedance Spectroscopy for the Statistical Process Control of Aluminum Anodizing--P. R. ROBERGE, E. HALLIOP, AND S. YOUSRI

313

Equivalent Circuit Modeling of Aluminum/Polymer Laminates Using Electrochemical Impedance Spectroscopy--G. R. T. SCHUELLER AND S. R. TAYLOR

328

Discussion

343

CORROSION OF STEEL IN SOIL AND CONCRETE Electrochemical Impedance of a Buried Large Structure--s. SUDO AND S. HARUYAMA

347

Calculation of Extended Counter Electrode Polarization Effects on the Electrochemical Impedance Response of Steel in Concrete--s. c. KRANC AND A. A. SAGOI~S

365

Discussion

383

Electrochemical Impedance and Harmonic Analysis Measurements on Steel in Concrete--M. I. JAFAR, J. L. DAWSON, AND D. G. JOHN

384

COATINGS ON METALS

Electrochemical Impedance of Coated Metal Undergoing Loss of Adhesion-M. W. KENDIG, S. JEANJAQUET, AND J. L U M S D E N

407

Analyzing and Interpreting Electrochemical Impedance Spectroscopy Data from Internally Coated Steel Aerosol Containers--w. s. TAIT, K. A. HANDRICH, S. W. TAIT, A N D J. W. MARTIN

428

Study of Protection Mechanisms of Zinc-Rich Paints by Electrochemical Impedance Spectroscopyms. FELIU, JR., R. BARAJAS, J. M. BASTIDAS, M. MORCILLO, A N D S. F E L I U

Evaluation of High-Performance Protective Coatings by Electrochemical Impedance and ChronoamperometrymR. D. GRANATA AND K. J. KOVALESKI Discussion

438

450 462

Improved Coatings Testing and Evaluation Using Electrochemical Impedance Spectroscopy--P. K A M A R C H I K

463

Author Index

475

Subject Index

477

ISBN 0-8031-1861-9

View publication stats